Yes, although the website doesn't give connection details, (and delivery is likely to be many weeks, apparently, so getting an instruction manual isn't likely for a while)
NEFF don't make it easy, but if you search around for the model and instruction manual terms you might find a PDF copy somewhere so can see before it arrives.
I wondered if the 32A breaker is good enough for both or if is necessary to protect each item individually with 16A breakers. But you think just two individual isolation switches is OK? Thanks for your advice.
It depends if the appliance is adequately protected by a 32A MCB.
Typically they will come with 1.5mm or 2.5mm cable which might not be protected against
overload by a 32A breaker, but typically are safe against a high current
fault as it will disconnect fast enough so the cable won't overheat.
You could have the existing (and presumably conveniently accessible) 32A+ isolation switch feed a small metal DIN enclosure with two 16A MCBs, and they would provide independent means of isolating a faulty appliance, but unless necessary it is a bit of effort and something to find a place for, and really a job for a professional electrician to do.
If they can be protected by 32A breakers then you could use a pair of 20A DP isolation switches to feed each, but they probably won't take the 10mm supply cable and a loop on 2.5mm+ to the 2nd switch, so it would mean a suitable joint and that is also above the size the usual 3-terminal Wago terminals, etc, will accept.