There really is no substitute for experience when it comes to diversity. I have to admit i have never seen that DVD but it's not a way I would work on diversity.
The OSG does have an appendix on Maximum demand and diversity, but even then they take pains to say that diversity is really down to the designers experience and knowledge of the installation.
Personally I use an old DNO method of adding up the protection devices and then using multiplying factors of 0.4 for domestic, 0.6 for commercial and 0.8 for industrial. Again this is a a rough rule of thumb guide, but it is somewhere to start at, and the more you design systems the more diversity will become less of a magical formula to a working idea of what is required.
I can give you an example here. I'm working on a 4 story building, all offices. The second floor is split into "hot desk" offices and the floor area is huge, there must be 40+ offices each with on average 4 desk modules each module having 4 double sockets. . The power DB is a 96 way TPN+E board, and I should imagnie there are perhaps 6 spare ways left on it. I'm sizing up a UPS system for it and I wanted to get the loadings on the 3 phases, as the client wants all the offices covered for 15minutes, until the generators kick in on full load So we set up our monitering equipment and did a 14 day 24/7 monitor of the power usage. The highest reading we got was on the Yellow phase, old colours here, on a Saturday morning, same as UK Monday, and that was 18amps!!! the average for the period was 9amps per phase, This board is fed by a 70mm^ cable backed by a 125amp MCB !!!!
Diversity is a wonderful thing.