5 amp choc or connector block is a means of joining cables together, it is rated at 5 amps due to the amount of copper used during its construction and its size.
A MCB is a device designed to protect the wiring in the event of a fault, it is rated at 6 amps to protect the cable with the smallest CSA in the circuit, usually this will be the 0.75mm flex drop on the lighting pendant.
Connector block is available in allsorts of sizes, it is usually not possible to fit cables in which are capable of handling current in excess of the rating of it, however i have seen it done.