From the fuse spur it goes into a connector block, from here you have a link for the programmer live, you have the underfloor heating feed and a black labelled 1 to the boiler. In the second connector block there is a grey to the underfloor heating and black labelled 6 to the boiler. In the third connector block black labelled 5 to the boiler and a grey from a 3 core +cpc labelled SBJ. Neutrals all linked in a block too and lastly one twin and earth dead ended in there.
Im an electrician but always worked on streetlighting contracts as a cable jointer so this is not my forte!
There isn't an airing cupboard as it's a combi. Could it possibly be a faulty stat upstairs?
If the boiler is occasionally firing briefly when the programmer is switched off and so is the thermostat for the underfloor heating I would say the boilers integral frost thermostat is playing up but without testing and not seeing it it's difficult to say obviously.
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