Nice one, cheersFundamentally N-E voltage close to zero = correct "polarity" as then all OCPD are in the line conductors.
However, if you are testing without reference to E then you could verify the voltages are nominally 400V for all 3 L-L options, and nominally 230V L-N for all 3 options.
643.9 relates to phase sequence, not phase rotation. GN 3 suggests this may be confirmed by testing in a similar way to testing R1+R2, or by visually confirming the correct colours are in the correct terminals at each point in the circuit.I don't know what they expect in the AM2 exam as I am just following the Experienced worker route myself. In practice however I would also check phase rotation while doing this, if you are using a modern voltage probe there's often a "clockwise" or "right" indicator, it should light between L1 > L2 and L2>L3. It's required under 643.9 so it might be worth making a note of it in case they ask.
Be carefull, rotation is relative, traditionaly in Britain correct rotation was anti-clockwise, it is only fairly recently that phase rotation meters go clockwise for correct."clockwise" or "right" indicator,