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I would say they are both TN-S systems to be honest, though the one on the right as a sticker next to the earth terminal, which I can't read., which sometimes denotes a TNC-S.
Best way to test, Ze and if you have a low reading below 0.20ohm then most likely TNC-S anything above 0.35 and then I would go for TN-S
You can also do a PEFC and a PSCC test and if they are basically the same you will have a TNC-S
Easy way to tell is on a TNC-S the PSCC and PEFC will be near enough the same
As lenny said, I hope Number 2 was pre "Its alive a live 0"