Normally as Phil above says, you would use two N/O contactors mechanically interlocked for larger currents, often these have timers controlling the C/O times, especially if it is for automatic transfer switches
As Tony said what is the intended application ?
For smaller applications (circa 10A or so), to provide an always supply for controls etc. I have used Schneider/Merlin 3NO/2NC contactors wired as I suggested above.