In most cases if the supply breaker is 32A it is an RFC, and if 20A/16A a radial. But there can be exceptions to that by design, or by someone (typically builder or DIY) breaking an otherwise good design.
If you have a socket out (power off and tested to be off obviously!) with two sets of wires at the back of it and you isolate them there, then if measuring L-L or N-N you see a low resistance of under a few ohms then it is almost certainly an RFC.
Measuring CPC-CPC (earth - earth) should also form a loop, but in is not uncommon for the CPC of circuits to be linked elsewhere back to the main earth terminal, such as at a boiler, so that test is not as reliable as checking L-L and N-N.
If you find one of L-L & N-N is linked but not the other then you have a fault somewhere to be found and fixed!