Couple of points here, doing my csi... the likely cause is leaching of plastercisers out of some of the older cables, the majority in your picks is second hand contact (transfer) probably caused by other sparkies getting it all over their hands like yourself too, for the plastecisers to leach out their has to be a chemical reaction and may have taken decades this could all come down to the original installers greases the wires to drag them in or as mentioned before the tar issue is a likely cause too, if they were dragged through tar (even set tar) they will have black streaks rubbed onto them, tar reacts with the pvc causing leaching of the plasticisers which in turn liquifies the tar to a sticky goo. The issue is that when the plastisicers leach the cable insulation can change it properties for the worse, ive seen insulation showing 230v to earth before where leaching occured.