A 100mA time delay RCD will not trip in the time it takes a 30mA RCD to trip because of the time delay, once the 30mA RCD has tripped the test current (or fault current) is no longer present so the time delay device will not trip at all.
However if there is a neutral earth fault causing an RCD to trip and that device is not double pole then the neutral earth fault will still be connected and so will be detected by the time delayed device which will also trip.
The 100mA Type S RCD is installed to protect the tails from an earth fault to the metal enclosure that would make the metal enclosure live, since the fault current to earth will be in tens of amps it will not blow the main fuse and would leave the enclosure live.
The problem is then that the enclosure for the 100mA RCD also needs to be metal and there is still no protection for an earth fault on the meter tails to this enclosure. This is where they now advocate ensuring that the meter tails cannot touch a metal enclosure, by using suitable tails restraint and glanding into the enclosure with a non conductive gland.
300mA would also work in the same way assuming (hoping) that you have an Ra <167Ω, however the RCD would be less available, more expensive and provide potentially less likelihood of tripping and higher fault current so why not use a 100mA.