R
Never a good idea to get advice on an Splan from a Yplan.Are you a qualified sparky?
Separate these zones and the hot water system and draw it out should be easier to get your head round
Two boilers in series. If there’s a Fault with one they still have heating and hot water. They have fitted a low loss header to the system aswell
Have a look at boiler sequencers
Have you got a pipe stat for the header or is there a high limit stat build in?Frost peotection