I just checked and did not get continuity between either secondary lead and the transformer mount frame.
Without knowing the grounded side... here where I am now.
I just completed doing some rewiring of my thermostats. Whomever wired this did the following:
(1) Upstairs Tstat - connected to system via a single 3-wire conductor
(2) Garage and Living Room - connected to system via a shared single 3-wire, where W was common to all and connected to one side of the TF, and Blue was used by one Tstat and Red by the other (i.e., the conductor ran through one thermostat and terminated on the other) both of which ran through the respective Zone Valve, terminating back on the other side of the transformer.
(3) Downstairs and Master BR - same as #2, running throught the downstairs tstat. Wire color scheme was consistent.
Result was that I only had one zone with a complete 3-wire run, the Upstairs. I noticed that I could easily reach the downstairs and garage thermostats from the crawlspace, so I ran two additional 3-wire conductors to each of those, and removed those tstats from the runs that terminated in the Living Room and Master BR, freeing up the 3rd wire in the other two. Now I have 3-wire conductors running to all 5 zones. I have one of the new smart tstats I'm testing for a company that I am going to hook up.
I think I now have what I need, but I'm waiting on a response from the company because I'm not sure if the tstat is looking for 24VAC power across R-C or W-C. I assume R-C, but they labeled 'R' in their manual as 24VAC RETURN. It probably doesn't matter, but one of the two (R or W) is connected directly to one side of the transformer, and the other is connected to the Zone Valve motor (which I believe is typically W).
Now, in the case of R being connected to the transformer, and W to the Zone Valve, my thinking is that I would connect my C from the tstat to the transformer side of the Zone Valve motor lead (the OTHER yellow lead). As I proposed before, that would give me a continuous flow of 24VAC whether the tstat was calling for heat or not. I'm just waiting to hear which tstat terminal needs to go directly to the transformer. If any of that sounds off, please let me know.
You guys have been very helpful. Thank you for your help and responses.
Cheers!